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Still Art Use:
Paint Shop Pro
Wings3D (if I really need a 3D object or text).
Sony Vegas Movie Studio HD (Pro is a tad too much for the videos I do!).
Otherwise, I do it "old skool" style (I started doing art in the cavemen days when paste up was the only way -- technical pens/quills (true calligraphy, yep); pica rulers; Zip-a-Tone; Diazo prints, etc.).