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I think EVE's UI is one of the best Ive see so far. The way information is linked is awesome.
Except keymapping. ctrl+shift+function key is not really userfriendly. Not letting players map shift+alphanumerical or just an alphanumerical key isnt either. I know that this has to do wth the way chat works, but other games usually have an option to change chatmode. So that you need to press enter first or click the box before typing. This would make more userfriendly shortcuts possible.
My keyboard has these tiny function keys and Im used to use all my shortcuts with just my left hand so my right hand stays on mouse (fps legacy). In EVE its as if Im playing piano because it doesnt accept single keys. Not to mention the stupid placing of the windows key between alt and ctrl (thanks Microsoft!).