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The lay of the land is.
ASUS GTX 660
AMD Sapphire 7950
I swapped the CPU's for obvious reasons. The issue was that the 27" screen would no properly resize to until I had uninstalled and reinstalled the Nvidia GTX 660 Drivers. Actually, the system more or less acted as if I didn't have any video card drivers until I had done said uninstall and reinstall.
On the other hand, I threw the 3570K into the Z77 did a restart and WHAM! Everything worked smoothly. No reinstall or uninstall necessary.
Does anyone know if there was a particular reason for this?